Nucleic acids

DNA and RNA: ng ↔ pmol, A260 quantification, Tm and copy number

Mass, moles, molecules and melting temperature for double-stranded DNA, single strands, RNA and synthetic oligonucleotides.

Mass ↔ moles for DNA and RNA ng ↔ pmol

Enter the length and either the mass or the amount. Molecular weight is estimated from average nucleotide masses (sodium salt).

MW ≈ length × 617.96 + 36.04 (dsDNA)  ·  n = m / MW
Molecule

Concentration from A₂₆₀

An A₂₆₀ of 1.00 at a 1 cm path length corresponds to 50 µg/mL dsDNA, 33 µg/mL ssDNA or oligo, and 40 µg/mL RNA.

concentration (µg/mL) = A₂₆₀ × factor × dilution ÷ path length

Oligonucleotide: MW, Tm and resuspension

Paste a primer or probe sequence. Molecular weight is calculated from the actual base composition, not an average.

Tm (GC rule) = 81.5 + 16.6·log₁₀[Na⁺] + 0.41·%GC − 600/length
PropertyValue

Plasmid / amplicon copy number qPCR standards

Convert a mass of double-stranded DNA into a molecule count, and plan a standard curve.

copies = (mass in g × 6.022×10²³) / (length in bp × 617.96)
StandardCopies / reactionConcentration

Constants used here

QuantityValueNote
Average MW per bp, dsDNA617.96 g/molsodium salt; + 36.04 for the two 5′-OH ends
Average MW per nt, ssDNA303.7 g/mol− 61.96 for a 5′-OH oligo
Average MW per nt, RNA320.5 g/mol− 61.96 for a 5′-OH transcript
A₂₆₀ = 1.0, dsDNA50 µg/mL1 cm path
A₂₆₀ = 1.0, ssDNA / oligo33 µg/mLhyperchromicity of the single strand
A₂₆₀ = 1.0, RNA40 µg/mL1 cm path
1 kb of dsDNA6.5 × 10⁵ g/moluseful mental shortcut
1 µg of 1 kb dsDNA1.52 pmol= 9.1 × 10¹¹ molecules

Purity ratios

  • A₂₆₀/A₂₈₀ ≈ 1.8 for DNA, ≈ 2.0 for RNA. Lower means protein or phenol; higher usually means RNA contamination of a DNA prep.
  • A₂₆₀/A₂₃₀ = 2.0–2.2. A low value points to guanidine, chaotropic salts, phenol or carbohydrate carryover — all common after column or Trizol preps.
  • Ratios are pH- and ionic-strength-dependent. Blank against the same buffer you eluted into, not water.

Which Tm formula to trust

The nearest-neighbour thermodynamic model (SantaLucia) is the accurate one and depends on the full sequence, salt and strand concentration. The two formulas here are the classic approximations:

  • Wallace ruleTm = 2(A+T) + 4(G+C). Only sensible below about 14 nt, and only at ~1 M salt.
  • GC/salt formula — reasonable for 14–70 nt oligos in standard PCR salt. Still typically ±3 °C against measured values.

For primer design, use both as a sanity check and set annealing temperatures around 3–5 °C below the lower estimate, then optimise empirically with a gradient.

Genome and vector sizes for reference

Genome / vectorSizeMass per haploid copy
pUC192 686 bp2.76 ag
Lambda phage48 502 bp49.7 ag
E. coli K-124.64 Mbp4.76 fg
S. cerevisiae12.1 Mbp12.4 fg
D. melanogaster180 Mbp185 fg
Human (haploid)3.1 Gbp3.18 pg

Frequently asked questions

How do I convert ng of DNA to pmol?

pmol = ng × 1000 / (bp × 617.96) for double-stranded DNA. 100 ng of a 3000 bp fragment is 100 × 1000 / (3000 × 617.96) = 0.054 pmol = 54 fmol.

What does an A260 of 1.0 correspond to?

For a 1 cm path length: 50 µg/mL double-stranded DNA, 33 µg/mL single-stranded DNA or oligonucleotide, and 40 µg/mL RNA.

What A260/A280 ratio indicates pure nucleic acid?

About 1.8 for DNA and 2.0 for RNA. Lower values suggest protein or phenol carryover; the A260/A230 ratio should also be roughly 2.0–2.2.

How do I calculate plasmid copy number for a qPCR standard curve?

copies = (mass in g × 6.022 × 10²³) / (plasmid length in bp × 617.96 g/mol). One nanogram of a 5000 bp plasmid contains about 1.95 × 10⁸ copies.

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