Recipes

Buffer and solution recipes

The solutions every lab makes constantly, each with the weigh-out calculation worked through, the procedure, and the mistakes that actually cost people a day.

The four rules that cover most buffer mistakes

  1. Check the salt form on the bottle. Hydrates and sodium salts have different formula weights — MgCl₂ is 95.21 g/mol anhydrous but 203.30 as the hexahydrate, and EDTA runs from 292.24 to 372.24 depending on form. Using the wrong number is the single most common weigh-out error.
  2. Titrate before making up to volume. Acid and base add volume.
  3. Titrate at the working temperature. Especially with Tris.
  4. Add divalent cations last, and never into a concentrated phosphate or carbonate solution, or you will precipitate them.

Frequently asked questions

Should I adjust pH before or after making up to volume?

Before. Titrating adds a real volume of acid or base — reaching pH 8.0 in a litre of 1 M Tris takes around 42 mL of concentrated HCl. Adjust the pH first, then make up to the final mark.

Why does my buffer read a different pH in the cold room?

Every buffer has a temperature coefficient, and Tris has an unusually large one (−0.028 pH units per °C). A Tris buffer set to pH 8.0 at 25 °C is near pH 8.6 at 4 °C. Titrate at the temperature you will use it at.

Can I autoclave any buffer?

Most, but not all. Autoclaving darkens Tris slightly, degrades glucose (autoclave it separately and add after), destroys most antibiotics, and precipitates calcium phosphate. Filter-sterilise anything heat-sensitive.

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